The 5th Brazilian Workshop on Chemometrics will be held at the Hotel Arembepe Beach (Arembepe, Bahia, Brazil) from the 9th to 11th of April, 2014 The program consists of: 5 mini-courses, 12 lectures, oral and poster presentations. The mini-courses are mainly focused in undergraduate and graduate students interested in learning chemometrics basic methods. The lectures will address different applications of chemometrics tools (http://www.vwquimiometria.ufba.br).